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Volume 15, Issue 5, 2006

LETTER: DELAMINATED POLYMER/LAMELLAR ALUMINOPHOSPHATE NANOCOMPOSITES PREPARED VIA IN SITU POLYMERIZATION

Jingyu Wang*, Guoping Chen, Quan Zhou

Department of Chemistry, Huangshan University, Huangshan, Anhui 245041, P.R. China

* Author to whom correspondence should be addressed, E-mail: wangjingyu@hsu.edu.cn

Received 8/2006; accepted 10/2006

ABSTRACT
A method to synthesize completely delaminated polymer/lamellar aluminophosphate (Mu-4) nanocomposites has been successfully developed, wherein organo-modification of Mu-4 followed by in situ polymerization was applied. It can be found that the long chain n-dodecylamine molecules can favor the intercalation of Mu-4 and thus readily make the Mu-4 layers delaminated in the polymer matrix compared with the short chain N,N-dimethylpropane-1,3-diamine.

KEYWORDS: Delamination, nanocomposite, aluminophosphate, in situ polymerization